The Serbian midfielder led his side to a 2-0 victory, ensuring they progress through to the FA Cup quarter-finals and in doing so earned 47% of fans' votes for the accolade.
Milivojevic claimed an assist for the Eagles' first goal as he laid-off Jeffrey Schlupp to set off a storming run down the pitch which resulted in Palace's opener.
Their second goal was then netted by German midfielder Max Meyer, who finished in second place with 25% of the Man of the Match vote.